Error apportionment for atmospheric chemistry-transport models – a new approach to model evaluation

نویسندگان

  • Efisio Solazzo
  • Stefano Galmarini
چکیده

In this study, methods are proposed to diagnose the causes of errors in air quality (AQ) modelling systems. We investigate the deviation between modelled and observed time series of surface ozone through a revised formulation for breaking down the mean square error (MSE) into bias, variance and the minimum achievable MSE (mMSE). The bias measures the accuracy and implies the existence of systematic errors and poor representation of data complexity, the variance measures the precision and provides an estimate of the variability of the modelling results in relation to the observed data, and the mMSE reflects unsystematic errors and provides a measure of the associativity between the modelled and the observed fields through the correlation coefficient. Each of the error components is analysed independently and apportioned to resolved processes based on the corresponding timescale (long scale, synoptic, diurnal, and intra-day) and as a function of model complexity. The apportionment of the error is applied to the AQMEII (Air Quality Model Evaluation International Initiative) group of models, which embrace the majority of regional AQ modelling systems currently used in Europe and North America. The proposed technique has proven to be a compact estimator of the operational metrics commonly used for model evaluation (bias, variance, and correlation coefficient), and has the further benefit of apportioning the error to the originating timescale, thus allowing for a clearer diagnosis of the processes that caused the error.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Interactive comment on “Error apportionment for atmospheric chemistry-transport models: a new approach to model evaluation” by E. Solazzo and S. Galmarini

Model/observation correlation as a stand-alone metric can be informative as it shows whether the model can reproduce patterns seen in the observations. For example, the ID component, as noted, has small errors, but for individual monitoring sites (not spatially averaged), correlation between modeled and observed ID is often quite low and insignificant (there often appears to be no relationship ...

متن کامل

An improved structure models to explain retention behavior of atmospheric nanoparticles

The quantitative structure-retention relationship (QSRR) of nanoparticles in roadside atmosphere against the comprehensive two-dimensional gas chromatography which was coupled to high-resolution time-of-flight mass spectrometry was studied. The genetic algorithm (GA) was employed to select the variables that resulted in the best-fitted models. After the variables were selected, the linear multi...

متن کامل

Modeling the Transport and Volumetric Properties of Solutions Containing Polymer and Electrolyte with New Model

A new theoretical model based on the local composition concept (TNRF-mNRTL model) was proposed to express the short-range contribution of the excess Gibbs energy for the solutions containing polymer and electrolyte. This contribution of interaction along with the long-range contribution of interaction (Pitzer-Debye-Hückel equation), configurational entropy of mixing (Flory-Huggins relation)...

متن کامل

Calibration method of numerical models in coastal sediment studies of Kuhmobarak area

Abstract Application of numerical models is useful in coastal sediment studies; however, it is essential to calibrate the models in an appropriate method. Empirical equations, historical satellite imagery and other coastal data and evidence are proposed for the models calibration in the vicinity of coastal indicators around the site of projects. In this study, coastal sediment process of K...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره   شماره 

صفحات  -

تاریخ انتشار 2016